个人简介

熊硕彦博士2017年毕业于中国科学技术大学，获高分子科学与工程工学学士学位。2023年在美国加州理工学院（Caltech）获化学博士学位（导师：Theodor Agapie教授）。2023年至今在美国加州大学伯克利分校（UC Berkeley）从事博士后研究，合作导师为美国科学院院士Jeffrey R. Long教授。曾获得国家优秀自费留学生奖学金，美国化学会无机化学部Young Investigator Award等。将于2025年8月加入西湖大学，建立可持续催化与可循环高分子材料实验室。

学术成果

熊硕彦博士的研究兴趣主要为在分子水平上精准理解和调控复杂反应过程及多相复杂系统；在此基础上，针对实现双碳目标以及满足国家对聚烯烃和新型环境友好材料的巨大需求，设计和开发高性能催化剂，可循环聚烯烃与功能高分子材料，以及新型反应装置等。熊硕彦博士在烯烃配位聚合机理研究与催化剂设计，聚合物微观结构调控以及聚烯烃升级循环等方面进行了系统的学习和研究，至今已在J. Am. Chem. Soc., Angew. Chem. Int. Ed., Adv. Mater., ACS Catal., Macromolecules, ACS Sustainable. Chem. Eng., Organometallics 等期刊发表论文近20篇，授权中国，美国专利各一项。

课题组目前致力于：

(1) 创制新型过渡金属催化剂，实现可循环功能化聚烯烃合成及聚烯烃可控降解；

(2) 设计新型吸附材料、催化体系和反应装置，实现二氧化碳捕集，活化及催化转化（聚合）；

(3) 开发废塑料升级转化方法及基于废塑料的功能材料。

代表论文（*代表通信作者, #代表同等贡献）

1. S. Xiong, A. Hong, B. C. Bailey, H. A. Spinney, H. Bailey, B. S. Henderson, S. Marshall, T. Agapie* "Acrylate-induced β-H elimination in coordination insertion copolymerization catalyzed by nickel" J. Am. Chem. Soc., 145, 26463-26471 (2023).

2. S. Xiong, A. Hong, B. C. Bailey, H. A. Spinney, T. D. Senecal, H. Bailey, T. Agapie* "Sterically sandwiched nickel phosphine enolate complexes: highly active, thermally robust catalysts for the synthesis of ethylene-acrylate copolymers" Angew. Chem. Int. Ed., 61, e202206637 (2022).

3. S. Xiong†, M. M. Shoshani†, X. Zhang†, H. A. Spinney, A. J. Nett, B. S. Henderson, T. F. Miller III*, T. Agapie* "Efficient copolymerization of acrylate and ethylene with neutral P,O-chelated nickel catalysts: mechanistic investigations of monomer insertion and chelate formation" J. Am. Chem. Soc., 143, 6516-6527 (2021).

4. P. Ghana†, S. Xiong†, A. A. Tekpor, B. C. Bailey, H. A. Spinney, B. S. Henderson, T. Agapie* "Catalyst editing via post-synthetic functionalization by phosphonium generation and anion exchange for nickel-catalyzed ethylene/acrylate copolymerization" J. Am. Chem. Soc., 146, 18797-18803 (2024).

5. S. Xiong, H. A. Spinney, B. C. Bailey, B. S. Henderson, A. A. Tekpor, M. R. Espinosa, P. Saha, T. Agapie* "Switchable synthesis of ethylene/acrylate copolymers by a dinickel-based system: evidence for chain growth on both nickel centers and concepts of cation shuttling polymerization" ACS Catal., 14, 5260-5268 (2024).

6. S. Xiong, P. Ghana, B. C. Bailey, H. A. Spinney, B. S. Henderson, M. R. Espinosa, T.Agapie* "Impact of labile ligands on catalyst initiation and chain propagation in Ni-catalyzed ethylene/acrylate copolymerization" ACS Catal., 13, 5000-5006 (2023).

7. S. Xiong, M. M. Shoshani, A. J. Nett, H. A. Spinney, B. S. Henderson, T. Agapie* "Nickel-based heterometallic catalysts in functional polar polyolefin synthesis: interrogating effects of secondary metal additives" Organometallics, 42, 2849-2855 (2023).

8. M. Bruening, S. Xiong, T. Agapie* "α,ω-Diene generation from ethylene and butadiene by copolymer upcycling" ACS Sustainable. Chem. Eng., 11, 9918-9923 (2023).

9. M. M. Shoshani†, S. Xiong†, J. Lawniczak, X. Zhang, T. F Miller III*, T. Agapie* "Phosphine-phenoxide nickel catalysts for ethylene/acrylate copolymerization: olefin coordination and complex isomerization studies relevant to the mechanism of catalysis" Organometallics, 41, 2119-2131 (2022).

10. M. P. Su, A. Aitbekova, M. Salazar, X. Zhang, S. Xiong, M. Espinosa, J. C. Peters, T. Agapie*, H. A. Atwater* "A photothermalcatalytic reactor and selective solar adsorber for sustainable fuel synthesis by ethylene oligomerization" Device, 3, 100604 (2024).

11. Z. Zhu†, H. Tsai†, S. T. Parker, J. Lee, Y. Yabuuchi, H. Jiang, Y. Wang, S. Xiong, A. C. Forse, B. Dinakar, A. Huang, C. Dun, P. J. Milner, J. Urban, J. A. Reimer, J. B. Neaton, J. R. Long* "High-capacity, cooperative CO₂ capture in a diamine-appended metal-organic framework through a combined chemisorptive and physisorptive mechanism" J. Am. Chem. Soc., 146, 6072-6083 (2024).

12. Z. Zhu, S. T. Parker, A. C. Forse, J. Lee, R. L. Siegelman, P. J. Milner, H. Tsai, M. Ye, S. Xiong, M. Paley, A. A. Uliana, J. Oktawiec, B. Dinakar, S. A. Didas, K. R. Meihaus, J. A. Reimer, J. B. Neaton, J. R. Long* "Cooperative carbon dioxide capture in diamine–appended magnesium–olsalazine frameworks" J. Am. Chem. Soc., 145, 17151-17163 (2023).

13. C. Tan, S. Xiong, C. Chen* “Fast and controlled ring-opening polymerization of cyclic esters by alkoxides and cyclic amides” Macromolecules, 51, 2048-2053 (2018).

14. J. Chen; Y. Gao; S. Xiong; T. L. Lohr; M. Delferro; T. J. Marks* “Metal and counteranion muclearity effects in organoscandium-catalyzed isoprene polymerization and copolymerization" ACS Catal., 7, 5214-5219 (2017).

15. S. Xiong, L. Guo*, S. Zhang, Z. Liu* “Asymmetric cationic [P,O]-type palladium complexes in olefin homo- and copolymerization” Chin. J. Chem., 35, 1209-1221 (2017).

联系方式

电子邮箱：xiongshuoyan@westlake.edu.cn

熊硕彦课题组长期开展高分子科学、催化化学、金属有机化学、化学工程、材料科学与工程等交叉领域的基础研究与应用基础研究。课题组鼓励成员依据个人研究兴趣选择研究课题，为成员提供具有国际竞争力的个人待遇和补助，并最大程度支持成员的未来职业发展。热忱欢迎对课题组相关研究方向感兴趣的青年学者加入我们！

课题组招收博士研究生，欢迎有博士入学申请意向的硕士生和本科生提前联系。具体招生信息请见西湖大学招生主页：https://www.westlake.edu.cn/admissions_aid/graduate/

课题组长期招收助理研究员、博士后、科研助理，也欢迎本科生加入从事短期研究。欢迎相关方向有激情、有能力的青年学者联系我们。申请者请发送个人简历以及感兴趣的研究方向至xiongshuoyan@westlake.edu.cn。